chemiluminescence properties of peroxyoxalate system in organic solvents

peroxyoxalate system includes an oxalate ester, peroxide and a fluorescer, the energy resulted from the reaction of oxalate ester and peroxide is transferred to fluorescer and cause it to fluorsc. the effect of reactants chemical structure, their concentration, solvent media (polarity and viscosity) and the temperature, on the intensity of the illuminated light with respect to time have been studied. the effect of chemical structure of oxalate ester, fluorescer and peroxide on the intensith of light was found to be follows: dnpo < tcpo < cbpo bpen < a < dpa < bpea tert-butylhydroperoxide < hydrogen peroxid